固体氧化物燃料电池电解质材料的研究

李静, 刘阿鹏

化工新型材料 ›› 2021, Vol. 49 ›› Issue (5) : 56 -59.

PDF (1380KB)
化工新型材料 ›› 2021, Vol. 49 ›› Issue (5) : 56-59. DOI: 10.19817/j.cnki.issn 1006-3536.2021.05.013
综述与专论

固体氧化物燃料电池电解质材料的研究

    李静, 刘阿鹏
作者信息 +

Research on electrolyte material for solid oxide fuel cells

  • Li Jing, Liu A'peng
Author information +
文章历史 +
PDF (1413K)

摘要

固体氧化物燃料电池(SOFC)作为一种新兴的绿色能源得到了广泛的关注,电解质作为关键材料,直接影响着电池的性能。分别介绍了SOFC常见的几种电解质材料,并分析了其各自的优缺点,低温化是SOFC的发展趋势,低温化不仅能降低成本,而且可以提高电池长期运行的稳定性,钙钛矿材料因其独特的优势有望成为低温化SOFC的首选材料。

Abstract

Solid oxide fuel cells (SOFCs) have received widespread attention as an emerging green energy source.Electrolytes,as key materials,directly affect battery performance.Several common electrolyte materials of SOFCs were introduced,and analyzed their advantages and disadvantages.The development trend of SOFCs was low temperature,which can not only reduce the cost,but also improved the long-term operation stability of the battery.Perovskite material was expected to become the preferred material for low temperature SOFCs due to its unique advantages.

关键词

固体氧化物燃料电池 / 钙钛矿结构电解质 / 离子电导率

Key words

solid oxide fuel cell / perovskite structure electrolyte / ionic conductivity

引用本文

引用格式 ▾
固体氧化物燃料电池电解质材料的研究[J]. 化工新型材料, 2021, 49(5): 56-59 DOI:10.19817/j.cnki.issn 1006-3536.2021.05.013

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 王绍荣,肖刚,叶晓峰.固体氧化物燃料电池[M].武汉:武汉大学出版社,2013,3-48.
[2] Godenough J B.Oxide-ion electrolytes[J].Annual Review of Materials Research,2003,33(1):91-128.
[3] Fergus J W.Electrolytes for solid oxide fuel cells[J].J Power Sources,2006,162(1):30-40.
[4] Sannan Yousaf Toor,Eric Croiset.Reducing sintering temperature while maintaining high conductivity for SOFC electrolyte:copper as sintering aid for samarium doped ceria[J].Ceramics International,2020,46:1148-1157.
[5] 苏峰.质子导体固体氧化物燃料电池的低温化研究[D].合肥:中国科学技术大学,2016.
[6] Thangadurai V,Weppner W.Synthesis and electrical properties of K-and Pr-substituted LaGaO3 and LaInO3 perovskites[J].Journal of the Electrochemical Society,2001,148(12):A1294-A1301.
[7] Kajitani M,Matsuda M,Hoshikawa A,et al.In situ neutron diffraction study on fast oxide ion conductor LaGaO3-based perovskite compounds[J].Chemistry of Materials,2005,17(16):4235-4243.
[8] Devanathan R,Thevuthasan S,Gale J D.Defect interactions and ionic transport in scandia stabilized zirconia[J].Physical Chemistry Chemical Physics,2009,11:5506-5511.
[9] Sarat S,Sammes N,Smimova A.Bismuth oxide doped scandia-stabilized zirconia electrolyte for the intermediate temperature solid oxide fuel cells[J].Journal of Power Sources,2006,160:892-896.
[10] Kinpton J,Randle T H,Drennan J.Investigation of electrical conductivity as a function of dopant-ion radius in the systems Zr0.75Ce0.08M0.17O1.92(M=Nd,Sm,Gd,Dy,Ho,Y,Er,Yb,Sc)[J].Solid State Ionics,2002,149:89-98.
[11] Takahashi T,Iwahara H,Nagai Y.High oxide ion conduction in sintered Bi2O3 containing SrO,CaO or La2O3[J].Journal of Applied Electrochemistry,1972,2(2):97-104.
[12] Miyayama M,Nishi T,Yanagida H.Oxygen ionic conduction in Y2O3-stablized Bi2O3 and ZrO2 composites[J].Journal of Materials Science,1987,22(7):2624-2628.
[13] 方俊鑫,殷之文.电介质物理学(第二版)[M].北京:科学出版社,1989,45-50.
[14] Wang S,Katsuki M,Hashimoto T,et al.Expansion behavior of Ce1-yGdyO2.0-0.5y under various oxygen partial pressures evalu-ated by HTXRD[J].Journal of Electrochemical Society,2003,150:952-958.
[15] Mogensen M,Sammes N M,Tompsett G A.Physical,chemical and electrochemical properties of pure and doped ceria[J].Solid State Ionics,2000(129):63-94.
[16] Steele B C H.Appraisal of Ce1-yGdyO2-y/2 electrolytes for IT-SOFC operation at 500℃[J].Solid State Ionics,2000,129:95-110.
[17] Ishihara T,Matsuda H,Takita Y.Doped LaGaO3 perovskitetype oxide as a new oxide ionic conductor[J].J Am Chem Soc,1994,116:3801.
[18] Steveson J W,Armstrong T R,Weber W J,et al.Processingand electrical properties of alkaline earth-doped lanthanum gallate[J].J Electrochem Soc,1997,144(10):3613.
[19] Mok C S,Ki T L,Kim S,et al.Oxygen ion conductivity and cell performance of La0.9Ba0.1Ga1-xMgxO3-δ[J].Solid State Ionics,2000,131:221.
[20] Huang K,Goodenough J B.A solid oxide fuel cell based on Sr-and Mg-doped La GaO3 electrolyte:the role of a rare-earth oxide buffer[J].Journal of Alloys and Compounds,2000,303-304:454-464.
[21] 师伟丽.Pr掺杂对La(Sr)Ga(Mg)O3电学性质的影响[D].哈尔滨:哈尔滨工业大学,2013.
[22] 王先平.钼酸镧系新型氧离子导体的氧离子扩散和导电机理研究[D].合肥:中国科学院研究生院(固体物理研究所),2003.

基金资助

山西省高等学校科技创新计划(2019L0988);山西工程技术学院“1331工程”校内培育项目(2019XF-04);阳泉市应用基础研究项目(2019G24)

AI Summary AI Mindmap
PDF (1380KB)

1039

访问

0

被引

导航
相关文章

AI思维导图

/